Product ID:EPA 8240B/8260A SYS PERFOR CHECK CMPD 1X1ML MEOH 2, 47389
MSDS Date:05/30/1996
FSC:6630
NIIN:00N091220
Status Code:A
MSDS Number: CJHVP

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

BENZENE, CHLORO-; (BENZENE, CHLORO-CHLOROBENZENE C*6H*5CL)

CAS: 108-90-7

RTECS: CZ0175000

OSHA PEL 350 MG/M3;75 PPM

ACGIH TLV: 46 MG/M3;10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHANE, 1,1-DICHLORO-; (ETHANE,

CAS: 75-34-3

RTECS: KI0175000

OSHA PEL 400 MG/M3;100 PPM

ACGIH TLV: 405 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHANE, 1,1,2,2-TETRACHLORO-; (ETHANE, 1,1,2,2-TETRACHLORO-

CAS: 79-34-5

RTECS: KI8575000

OSHA PEL 35 MG/M3;5 PPM

ACGIH TLV: 6.9 MG/M3;1 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHANE, CHLORO-; (METHANE, CHLORO- CHLOROMETHANE CH*3CL)

CAS: 74-87-3

RTECS: PA6300000

OSHA PEL see Table Z-2

ACGIH TLV: 103 MG/M3;50 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHANE, TRIBROMO-; (METHANE, TRIBROMO- BROMOFORM CHBR*3)

CAS: 75-25-2

RTECS: PB5600000

OSHA PEL 5 MG/M3;0.5 PPM

ACGIH TLV: 5.2 MG/M3;0.5 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

5628 MG/KG

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL 260 MG/M3;200 PPM

ACGIH TLV: 262 MG/M3;200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:SEE INGREDIENTS SECTION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. LOW BLOOD PRESSURE (HYPOTENSION). DERMATITIS. BREATHING
DIFFICULTY. HEADACHE. NAUSEA. DIZZINESS. GASTROINTESTINAL
DISTURBANCES. DEPRESSES CENTRAL NERVOUS SYSTEM. NARCOSIS. LIVER
AND KIDNEY DAMAGE. REPORTED ANIMAL CARCINOGEN. RESPIRATORY FAILURE.
BLINDNESS. MAY CAUSE CORNEAL INJURY.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CONTACT MD.
SKIN: FLUSH WITH LARGE VOLUMES OF WATER. WASH CLOTHING AND SHOES
BEFORE REUSE. INHALATION: IMMEDIATELY MOVE TO FRESH AIR. GIVE
OXYGEN IF BRE ATHING IS LABORED. IF BREATHING STOPS, GIVE
ARTIFICIAL RESPIRATION. CONTACT MD. INGESTION: NEVER GIVE ANYTHING
BY MOUTH TO AN UNCONSCIOUS PERSON. NEVER TRY TO MAKE AN UNCONSCIOUS
PERSON VOMIT. GIVE 2 TABLESPOONS OF BAKING SODA IN A GLASS OF
WATER. PRESS FINGERS TO BACK OF TONGUE TO INDUCE VOMITING.
IMMEDIATELY CONTACT MD.

Flash Point:=10.C, 50.F
Lower Limits:6.0%
Upper Limits:36.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMPOSITION: CARBON MONOXIDE,
CARBON DIOXIDE, FORMALDEHYDE, HYDROGEN CHLORIDE, PHOSGENE,
CHLORINE.

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. ELIMINATE ALL IGNITION SOURCES.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION SOURCES.
Other Precautions:AVOID EYE OR SKIN CONTACT. AVOID BREATHING VAPORS.

Respiratory Protection:WEAR NIOSH APPROVED FACE MASK WITH ORGANIC VAPOR
CANISTER.
Ventilation:USE ONLY IN A WELL VENTILATED AREA.
Protective Gloves:WEAR RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER .
Supplemental Safety and Health

Boiling Pt:=65.C, 149.F
Melt/Freeze Pt:=-98.C, -144.4F
Vapor Pres:100 MM
Vapor Density:1.1(AIR=1)
Spec Gravity:0.790
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:100%
Appearance and Odor:CLEAR COLORLESS LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE,
PERCHLORIC ACIDS, ALUMINUM AND MAGNESIUM. METALS.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
FORMALDEHYDE, HYDROGEN CHLORIDE, PHOSGENE, CHLORINE.

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE, OR
LOCAL REGULATIONS.

Toxicological Information:LD50 5628 MG/KG ORAL RAT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

SARA Title III Information:METHANOL, BENZENE, CHLORO-, ETHANE,
1,1,2,2-TETRACHLORO-, METHANE, CHLORO-, METHANE, TRIBROMO-, ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF SARA TITLE III, SECTION
313.
State Regulatory Information: